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Beilstein J. Org. Chem. 2010, 6, 1120–1126, doi:10.3762/bjoc.6.128
Graphical Abstract
Figure 1: Representative olefin metathesis catalysts.
Figure 2: Highly active olefin metathesis catalysts bearing NHC with backbone substitution.
Scheme 1: Synthesis of the free NHCs.
Scheme 2: Synthesis of [RhCl(CO)2(NHC)] complexes.
Scheme 3: Synthesis of [RuCl2(NHC)(PCy3)(Ind)] complexes.